The development of a promising photosensitive Schottky barrier diode using a novel Cd(II) based coordination polymer

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dc.contributor.author Ghorai, P.
dc.contributor.author Dey, A.
dc.contributor.author Brandao, P.
dc.contributor.author Ortega-Castro, J.
dc.contributor.author Bauza, A.
dc.contributor.author Frontera, A.
dc.contributor.author Ray, P.P.
dc.contributor.author Saha, A.
dc.date.accessioned 2023-10-03T07:27:21Z
dc.identifier.uri http://hdl.handle.net/11201/161836
dc.description.abstract [eng] A novel 1D Cd(II) based coordination polymer (complex 1) has been synthesized involving an 8-aminoquinoline based Schiff base ligand and cyanate ion. It has been characterized by elemental analysis, different spectroscopy methods and X-ray single crystal diffraction technique. Most interestingly it exhibits unique properties like electrical conductivity and photosensitivity which shows its potential in optoelectronic device application. We prove both experimentally and theoretically that electrical conduction under irradiation of visible light increases many fold in comparison with that under dark condition. Our synthesized material based device shows some paramount behaviour under irradiance of light which is obvious in light sensing Schottky devices. The rectification ratio of our complex based device was found to be 12.44 and 27.74 under dark and photoirradiation conditions respectively. The discovery of such type of coordination polymer advances the area of optoelectronic devices.
dc.format application/pdf
dc.relation.isformatof Versió postprint del document publicat a: https://doi.org/10.1039/C7DT02535A
dc.relation.ispartof Dalton Transactions, 2017, vol. 46, num. 39, p. 13531-13543
dc.rights (c) Ghorai, P. et al., 2017
dc.subject.classification 54 - Química
dc.subject.other 54 - Chemistry. Crystallography. Mineralogy
dc.title The development of a promising photosensitive Schottky barrier diode using a novel Cd(II) based coordination polymer
dc.type info:eu-repo/semantics/article
dc.type info:eu-repo/semantics/acceptedVersion
dc.date.updated 2023-10-03T07:27:22Z
dc.date.embargoEndDate info:eu-repo/date/embargoEnd/2100-01-01
dc.embargo 2100-01-01
dc.subject.keywords Cd (II)
dc.subject.keywords Polymer chemistry
dc.subject.keywords diode oscillator
dc.rights.accessRights info:eu-repo/semantics/embargoedAccess
dc.identifier.doi https://doi.org/10.1039/C7DT02535A


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